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Dr. James H. Williams

Visiting Assistant Professor

4201 Grant Line Road

New Albany, Indiana 47150

 

812-941-2267

Fax: 812-941-2637

jahwilli@ius.edu


EDUCATION                           

Columbia University; New York, New York

Master of Business Administration

Concentration: Finance

 

University of Louisville; Louisville, Kentucky

Ph.D.

 

Saint Louis University; St. Louis, Missouri

Master of Science in Research

 

Kent State University; Kent, Ohio

Bachelor of Science Degree

 

 

 

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Courses Taught

CHEM. C341 ORGANIC CHEMISTRY LECTURES 1  (3 CR HR)
Chemistry of carbon compounds. Nomenclature; qualitative theory of valence; structure and reactions. Syntheses and reactions of major

classes of monofunctional compounds.

CHEM. C342 ORGANIC CHEMISTRY LECTURES 2
Syntheses and reactions of polyfunctional compounds, natural and industrial products; physical and chemical methods of identification. (3 CR HR)

CHEM. C343 ORGANIC CHEMISTRY LABORATORY 1
Laboratory instruction in the fundamental techniques of organic chemistry and the use of general synthetic methods. (2 CR HR)
 

CHEM. C102 ELEMENTARY CHEMISTRY I (3 CR HR)

The chemistry of organic compounds and their reactions including an extensive introduction to biochemistry.

 

CHEM. C104 PHYSICAL SCIENCES & SOCIETY (3 CR HR)

An integrated survey of modern applications and relationships of physical sciences to society.

 

CHEM. C122 ELEMENTARY CHEMISTRY LABORATORY II
Emphasis on organic and biochemical experimental techniques.(2 CR HR)

 

CHEM.  C398  PROF PRACTICE IN CHEMISTRY (1-6 CR)
Independent Study related to writing a scientific paper

 

CHEM. 390 Undergraduate Independent Study (1-3 cr.)

Independent research based on existing literature or original work. A report, in the style of a departmental technical report, is required.

 

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Patents & Thesis & Publications

Ph.D. Thesis: Reactivity of Unsaturated Heterocycles and Synthesis of 1,2,5,8-tetrahydro-3H-pyrrolizine & Reactions of

Mucobromic Acid Derivatives with Primary Amines and Iodine Azide

Goal: Synthesis of anticancer drugs with the basic structure of Mytomycin C

 

MS Thesis: The Electrochemistry of 1,3-Diketones

Goal: To electrochemically synthesize a postulated cyclopropane intermediate in the well known Clemmensen reduction of 1,3-diketones.

 

Patent No.                  United States Patent Title                                                                                             Date Filed

 

4,225,680        Urea for Foam with Low Shrinkage                                                                                          8/6/1979

4,343,718        Aqueous Foaming Agent Solution                                                                                             4/17/1980

4,409,293        Wood Composites of Low Formaldehyde Emission                                                                 10/11/1983

4,501,851        Urea-Formaldehyde Precursor                                                                                                  2/28/1984

4,482,699        Low Emitting Aqueous Formulations of Aminoplast

                        Resins and Process for Manufacturing Them                                                                          9/25/1983

4,410,685        Hydrolytically Stable Urea-Formaldehyde Resins and Process for Manufacturing Them    9/10/1982                      

4,530,713        Urea-Formaldehyde Suspension                                                                                                7/25/1983

 

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Undergraduate Research Projects

 

I have two areas of interest for students who want to be involved in undergraduate research.

The areas are solar energy and environmental friendly fertilizers.

Solar energy

A solar (photovoltaic, or PV) cell kit, using natural dyes that can be extracted from berries, is manufactured and distributed by the Institute for Chemical Education (ICE). The solar cell kit is based on work relating to nanocrystalline dye-sensitized solar cells that use an organic dye to absorb incoming light to produce excited electrons. The student will begin independent research by first writing a summary paper that outlines and discusses the subject of nanocrystalline dye-sensitized solar cells including the current research efforts and progress. The paper will end with a proposed area of research for the student to follow with the solar kit in following semesters.
 

The solar energy research project provides an interdisciplinary context for students to learn the basic principles of biological extraction, chemistry, physics, environmental science and electron transfer. The project is designed to inspire a new generation of researchers while teaching the basic principles of chemistry, physics, biology and environmental policy.


 For those students interested in reading more about the subject of nanocrystalline dye-sensitized solar cell technology

please refer to the following external sources.

 

External Resources

Materials Research Science and Engineering Center on Nanostructured Materials and Interfaces

The Swiss Federal Institute of Technology

Nanocrystalline Solar Cell technology

Australian Artificial Photosynthesis Network

Nanocrystalline Dye-Sensitized Solar Cell Kit

Journal of Chemical Education

Energy Efficiency and "Renewable Energy web page from the US Department of Energy

Laboratory for Photonics & Interfaces

Solar hydrogen: the search for water-splitting materials brightens up

Optoelectronics Projects

Titanium Dioxide Raspberry Solar Cell

Solar - US Department of energy


 

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Environmental Friendly Fertilizers

 

Nitrogen, phosphorus and potassium are the main plant nutrients needed for plant growth. Nitrogen is required in the largest amounts to grow healthy turfgrass. Consequently, N fertilizers are applied more often, and in larger quantities, than all the other nutrients combined.

 

A water soluble fertilizer can be easily converted into a plant available form when it is added to the soil to give quick green-up and growth. Ammonium, nitrate and urea are the most common ingredients of quick release nitrogen. A steady level of growth over the entire growing season from one application is more suitable. The slow release fertilizers are synthetically manufactured products and depend on microbial activity in the soil to break down the fertilizers into plant available forms.

 

Many causes of pollution including sewage and fertilizers contain nutrients such as nitrates and phosphates.  In excess levels, nutrients over stimulate the growth of aquatic plants and algae.  Excessive growth of these types of organisms consequently clogs our waterways, use up dissolved oxygen as they decompose, and block light to deeper waters. This, in turn, proves very harmful to aquatic organisms as it affects the respiration ability or fish and other invertebrates that reside in water. "Eutrophication", by definition, is the enrichment of surface waters with plant nutrients and both nitrogen and phosphorus compounds from fertilizer applications contribute to eutrophication.

 

Fertilization of surface waters (eutrophication) results in, for example, explosive growth of algae which causes disruptive changes to the biological equilibrium [including fish kills]. This is true both for inland waters (ditches, river, and lakes) and coastal waters. Groundwater is also being polluted mainly by nitrates and in several areas, the groundwater is polluted to an extent that it is no longer fit to be used as drinking water according to present standards.

 

The pollution issues and the high cost of manufacturing environmentally friendly slow release fertilizers, offers an opportunity to conduct research in the following areas of interest.

 

·         Covalently linking phosphorus and nitrogen within the same molecule to minimize leaching.

·         Synthesizing a synthetic organic fertilizer compound with high water insoluble nitrogen in a one step batch reaction.

 

The fertilizer research project provides an interdisciplinary context for students to learn the basic principles of chemistry, environmental science and biology. It will also offers a cross functional opportunity to evaluate the efficacy of the synthetic products through a joint research effort with the biology department at IUS. The project is designed to inspire a new generation of researchers while teaching the basic principles of chemistry, biology and environmental policy. The student will use synthetic methods in the laboratory to synthesis compounds along with instrumentation such as GC-MS chromatography, H1 and C13 NMR, UV and IR spectroscopy and HPLC to follow the reactions and identify the final products.
 

For those students interested in reading more about the subject of fertilizers,

please refer to the following external sources.

 

External Resources

Slow- Release Fertilizers

Urea as a source of fertilizer nitrogen for crops in Kentucky
Fertilizer.com web site

Fertilizer Urea

Tennessee Valley Authority (TVA)

Department of Agriculture's science magazine

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Web Links for Chemistry Students

ScienceFinder (On various desk tops in our IUS main library)

 

Scifinder Resources ( Tutorial site for ScienceFinder)

This site provides pathways to published research in the world's journal and patent literature–virtually everything relevant to chemistry plus a wealth of information in the life sciences and a wide range of other scientific disciplines back to the beginning of the 20th century. Chemical Abstract Service provides this search engine. Please use the "Scifinder Resources" link to learn how to search on this engine. This is the best of all sites for us chemists.
ChemWeb ChemWeb.com provides access to the information chemists need to enhance their research, product development, self-development, education, and/or their businesses in Chemistry and related disciplines.
ChemFinder Enter a Chemical Name, CAS Number, Molecular Formula or Weight. A good site for finding the identity of a chemical structure.
Scirus

Scirus is a comprehensive science-specific search engine that searches over 200 million science-specific Web pages. It will give Chemistry 340 series organic students an opportunity to search the literature for specific issues they want to address for a class or laboratory effort.

United States Patent and Trademark Office This web site belonging to the USPTO is an excellent place to start searching for prior art relating to the patenting of new and novel chemical ideas and concepts.
National Library of Medicine

Search for books, journal and audiovisual titles in the NLM collections -  Locator homepage will give you a link to various ways to search. You will have access to "PubMed and Medline Plus".

Chemistry.org Website of the American Chemical Society. Check it out.
Institute for Chemical Education ICE was established in 1983 to provide a center for science educators to develop and disseminate ideas. ICE is national in scope and has led the drive to help teachers revitalize science in schools throughout the United States.
Journal of Chemical Education This is a great site for students on the area of chemical education. Also good for searching the latest in research articles relating to chemistry.
Internet Chemistry Directories Spectroscopy, chromatography, physical chemistry, chemical compound naming and chemistry link sites
Chemical Society The site provides interesting features and useful services for the chemistry community. The information you find has been made available by various national chemistry societies for dissemination on a single site. Currently around 30 such societies are providing varying levels of information on chemsoc.
Chemistry Fun & Humor This web site is offered a an opportunity to relax and have some fun when courses get you down.
JCE ChemInfo: Organic This site is a collection of Web pages containing information useful to teachers, researchers, and students in organic chemistry, biochemistry, and medicinal chemistry. The pages have been selected for ease of use, broad applicability, and quality of coverage. Topics will include structural information, organic reactions, nomenclature, physical properties, and spectroscopic data.
Chemistry Cartoons This is another web site that offers an opportunity to relax and have some fun when courses get you down.
http://www.chemsoc.org/networks/learnnet/w-spectra-organic.htm           This is a great web site for organic students who need to gather FTIR and NMR spectroscopic data for their laboratory experiments.
http://webbook.nist.gov       The National Institute of Science and Technology offers spectrographic and chemical data on organic compounds.
http://www.sigmaaldrich.com     Sigma-Aldrich offers access to their data base of organic properties.
http://www.americanelements.com/

The American Elements website is a source for academic investigation and research information relative to the basic elements in the periodic chart. Check out the information available for each of the elements.

WWW Chemistry Guide WWW Chemistry Guide - a comprehensive collection of annotated links for chemists and researchers involved in organic, biochemical, computational, medicinal and/or other chemistry research.

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Last updated: 12 December 2005
URL: http://homepages.ius.edu/jahwilli/
Send comments to: jahwilli@ius.edu